dor_id: 4107955

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650.#.4.x: Físico Matemáticas y Ciencias de la Tierra

336.#.#.b: info:eu-repo/semantics/article

336.#.#.3: Artículo de Investigación

336.#.#.a: Artículo

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856.4.0.u: https://rmf.smf.mx/ojs/rmf/article/view/Vol.%2064%2C%20Issue%203%2C%20pp.%20240-250/96; https://rmf.smf.mx/ojs/rmf/article/downloadSuppFile/Vol.%2064%2C%20Issue%203%2C%20pp.%20240-250/28

100.1.#.a: Diaz Reyes, Joel; Contreras Rascón, Jorge Indalecio; Linares Avilés, Mariana Enelia; Sánchez Ramírez, José Francisco; Flores Mena, José Eladio; Castillo Ojeda, Roberto Saul; Peralta Clara, Maria de la Cruz; Veloz Rendón, Julieta Salom

524.#.#.a: Diaz Reyes, Joel, et al. (2018). Rare earths (Ce, Eu) molar concentration-dependent of the structural and optical properties of CBD-CdS nanofilms. Revista Mexicana de Física; Vol 64, No 3 May-Jun: 240-250. Recuperado de https://repositorio.unam.mx/contenidos/4107955

245.1.0.a: Rare earths (Ce, Eu) molar concentration-dependent of the structural and optical properties of CBD-CdS nanofilms

502.#.#.c: Universidad Nacional Autónoma de México

561.1.#.a: Facultad de Ciencias, UNAM

264.#.0.c: 2018

264.#.1.c: 2018-04-30

653.#.#.a: CdS, Chemical bath deposition, Rare earths, cerium, europium

506.1.#.a: La titularidad de los derechos patrimoniales de esta obra pertenece a las instituciones editoras. Su uso se rige por una licencia Creative Commons BY-NC-ND 4.0 Internacional, https://creativecommons.org/licenses/by-nc-nd/4.0/legalcode.es, fecha de asignación de la licencia 2018-04-30, para un uso diferente consultar al responsable jurídico del repositorio por medio de rmf@ciencias.unam.mx

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001.#.#.#: oai:ojs.rmf.smf.mx:article/72

041.#.7.h: eng

520.3.#.a: It presents the characterization of rare earths (Eu,Ce)-doped CdS nanofilms that were synthesised by the growth technique chemical bath deposition (CBD) at the reservoir temperature of 70±2°C. The doping of CdS with rare earths is performed by varying the synthesis time from 60 to 135 min. The rare earths molar concentration was range from 0.0≤x≤3.5, which was determined by energy dispersive X-ray spectroscopy. X-ray diffraction (XRD) analysis and Raman scattering reveal that CdS nanofilms showed the zinc blende (ZB) crystalline phase. The CdS average nanocrystal size was ranged from 1.84 to 2.67 nm that was determined by the Debye–Scherrer equation from ZB (111) direction, which was confirmed by transmission electron microscopy. Raman scattering shows that the lattice dynamics is characteristic of bimodal behaviour and the multipeaks adjust of the first optical longitudinal mode for the (Eu,Ce)-doped CdS, which denotes the Raman shift of the characteristic peak about 305 cm−1 of the CdS nanocrystals. The CdS nanofilms exhibit a direct bandgap that slightly decreases with increasing doping, from 2.50 to 2.42 eV, which was obtained by room temperature transmittance. The room-temperature photoluminescence of CdS shows the band-to-band transition at 2.88 eV, which is associated to quantum confinement and a dominant radiative band at 2.37 eV that is called the optical signature of interstitial oxygen. The Eu3+-doped CdS photoluminescence shows the dominant radiative band at 2.15 eV, which is associated to the intra-4f radiative transition of Eu3+ ions that corresponds to the magnetic dipole transition, (5D0→7F1). For the Ce3+-doped CdS the dominant radiative transition, at 2.06 eV, is clearly redshifted, although the passivation of the CdS nanofilms by Ce was approximately by a factor about 21 for the best results.

773.1.#.t: Revista Mexicana de Física; Vol 64, No 3 May-Jun (2018): 240-250

773.1.#.o: https://rmf.smf.mx/ojs/rmf/index

046.#.#.j: 2020-11-25 00:00:00.000000

022.#.#.a: 2683-2224 (digital); 0035-001X (impresa)

310.#.#.a: Bimestral

264.#.1.b: Sociedad Mexicana de Física, A.C.

758.#.#.1: https://rmf.smf.mx/ojs/rmf/index

doi: https://doi.org/10.31349/RevMexFis.64.240

handle: 27a83e0977c29263

harvesting_date: 2020-09-23 00:00:00.0

856.#.0.q: application/pdf

last_modified: 2020-11-27 00:00:00

license_url: https://creativecommons.org/licenses/by-nc-nd/4.0/legalcode.es

license_type: by-nc-nd

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Artículo

Rare earths (Ce, Eu) molar concentration-dependent of the structural and optical properties of CBD-CdS nanofilms

Diaz Reyes, Joel; Contreras Rascón, Jorge Indalecio; Linares Avilés, Mariana Enelia; Sánchez Ramírez, José Francisco; Flores Mena, José Eladio; Castillo Ojeda, Roberto Saul; Peralta Clara, Maria de la Cruz; Veloz Rendón, Julieta Salom

Facultad de Ciencias, UNAM, publicado en Revista Mexicana de Física, y cosechado de Revistas UNAM

Licencia de uso

Procedencia del contenido

Entidad o dependencia
Facultad de Ciencias, UNAM
Revista
Repositorio
Contacto
Revistas UNAM. Dirección General de Publicaciones y Fomento Editorial, UNAM en revistas@unam.mx

Cita

Diaz Reyes, Joel, et al. (2018). Rare earths (Ce, Eu) molar concentration-dependent of the structural and optical properties of CBD-CdS nanofilms. Revista Mexicana de Física; Vol 64, No 3 May-Jun: 240-250. Recuperado de https://repositorio.unam.mx/contenidos/4107955

Descripción del recurso

Autor(es)
Diaz Reyes, Joel; Contreras Rascón, Jorge Indalecio; Linares Avilés, Mariana Enelia; Sánchez Ramírez, José Francisco; Flores Mena, José Eladio; Castillo Ojeda, Roberto Saul; Peralta Clara, Maria de la Cruz; Veloz Rendón, Julieta Salom
Tipo
Artículo de Investigación
Área del conocimiento
Físico Matemáticas y Ciencias de la Tierra
Título
Rare earths (Ce, Eu) molar concentration-dependent of the structural and optical properties of CBD-CdS nanofilms
Fecha
2018-04-30
Resumen
It presents the characterization of rare earths (Eu,Ce)-doped CdS nanofilms that were synthesised by the growth technique chemical bath deposition (CBD) at the reservoir temperature of 70±2°C. The doping of CdS with rare earths is performed by varying the synthesis time from 60 to 135 min. The rare earths molar concentration was range from 0.0≤x≤3.5, which was determined by energy dispersive X-ray spectroscopy. X-ray diffraction (XRD) analysis and Raman scattering reveal that CdS nanofilms showed the zinc blende (ZB) crystalline phase. The CdS average nanocrystal size was ranged from 1.84 to 2.67 nm that was determined by the Debye–Scherrer equation from ZB (111) direction, which was confirmed by transmission electron microscopy. Raman scattering shows that the lattice dynamics is characteristic of bimodal behaviour and the multipeaks adjust of the first optical longitudinal mode for the (Eu,Ce)-doped CdS, which denotes the Raman shift of the characteristic peak about 305 cm−1 of the CdS nanocrystals. The CdS nanofilms exhibit a direct bandgap that slightly decreases with increasing doping, from 2.50 to 2.42 eV, which was obtained by room temperature transmittance. The room-temperature photoluminescence of CdS shows the band-to-band transition at 2.88 eV, which is associated to quantum confinement and a dominant radiative band at 2.37 eV that is called the optical signature of interstitial oxygen. The Eu3+-doped CdS photoluminescence shows the dominant radiative band at 2.15 eV, which is associated to the intra-4f radiative transition of Eu3+ ions that corresponds to the magnetic dipole transition, (5D0→7F1). For the Ce3+-doped CdS the dominant radiative transition, at 2.06 eV, is clearly redshifted, although the passivation of the CdS nanofilms by Ce was approximately by a factor about 21 for the best results.
Tema
CdS, Chemical bath deposition, Rare earths, cerium, europium
Idioma
eng
ISSN
2683-2224 (digital); 0035-001X (impresa)

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